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Silver,nickle plating info and molds
Original poster: "Allan Scott" <ascott16-at-cogeco.ca>
PLASTIC FORMULAS
Look around you. Almost everything you see is made of plastic. Now with
these 16 formulas you can
make your own items, such as lamps, plaques, vases, toys, desk sets,
novelty items and more. It's an
endless list. The only requirement needed is a small space to work in, a
heater or stove. You need a
kettle or pan to heat the mixture in and a table or bench to work on. Your
dining table can be used.
SULPHO-PLASTICS
This plastic is particularly adaptable for making molds and light castings
requiring low tensile strength
but very clear outline. It may also be used for making novelties and
ornaments. However, as this is
inflammable, do not use for ashtrays.
The name would convey the thought of plastic sulphur which is an unstable
allotropic for of sulphur,
this is not the case. The sulphur acts as a bond to hold the filler
together and form a stable material.
Marble effects may be obtained by varying the filler used, and by
substituting a small quantity of chalk
to replace some of the graphite. A very pleasing glazed marble effect is
formed.
As long as graphite is retained as a filler, this plastic may be
electroplated and forms a very economical
base for such work.
FORMULA: Mix thoroughly and smooth together 25 parts graphite and 75 parts
sulphur and place
over low heat. As soon as the mass has melted and runs like water, remove
from heat. In any case, a
temperature of 235 degrees F. should not be exceeded. It heated about 250
degrees F. the plastic will
form a rubbery mass and will have to be cooled and reheated. In this liquid
state the plastic is ready for
casting, and may be poured into smooth surfaced molds.
N.B. to heat this mixture properly, a good even heat is necessary. Should
the heating be done by flame,
the container should be placed in a sand bath to insure an even heat. The
cast iron top of a stove or
heater is excellent.
EQUIPMENT: The only equipment for the above that is required, is space
enough to work. a heater or
stove, a kettle or pan to heat the mixture in, and a table or bench.
PROCEDURE: Before making in castings you will need a pattern. After
choosing a design that fits
your need, your next step is to make a mold. Then you start into
production. If your product requires
any holes, threads or machining, this may be done in the same manner as in
working with a metal
casting.
Always think of your castings as metal, for they have metallic properties,
i.e., conduct heat, electricity
and can be electroplated. In fact, the most valuable quality of
Sulpho-Plastic is the fact that it can be
used as a metal substitute. This permits you to make products that look and
are as good and even
better, in some cases, than a true metal. For instance, to make a chrome
plated metal lamp base, other
metal casting would require foundry equipment and machine shop work. A
process miles out of reach
of the small manufacturer. However, with your plastic lamp base, similar in
all respects, may be made
for a fraction of the other cost.
ELECTROPLATING: While this can be done at home with very little equipment,
it is advisable to
have it done by a commercial form. They do it very cheaply and much more
efficiently. Electroplating
is only used on expensive replicas and is not advisable for a start.
DESIGN: The number and variety of articles that can be made from
Sulpho-Plastic is practically
unlimited and to make a complete list would be impossible. Though any
article of reasonable size and
simplicity of design such as lams, vases, plaques, brooches, desk-sets,
toys, paper weights, etc., may be
cast by using an original article for a pattern or model. Or an original
design may be patterned in clay
and used to make a mold. It is advisable for the beginner to choose a
simple article to start with,
preferably solid, such as book-ends or paper weights.
MOLDS: Molds may be made of metal or plaster of paris. Metal models require
a great deal of skill
and equipment to produce. therefore for the beginner, it is advisable to
use plaster of paris.
To make a plaster of paris mold. First obtain a box, wood or cardboard,
about an inch larger than the
article to be cast. Coat the inside of the box very thoroughly, yet thinly
with stearine or sweet oil. Use
this also on the article to be cast. This acts as a lubricant and the
plaster of paris will not cement itself
to either the box or the article, if the oil is evenly distributed. Next
make a thick, creamy mixture of
plaster of paris by sifting the plaster gradually into the water, stirring
constantly to prevent lumping. Let
this stand for a few minutes to allow the air bubbles to escape. Pour
mixture slowly over pattern in the
box to about double the thickness of the pattern. Allow several hours to
dry, then remove. when the
mold is thoroughly dry, give it a thin coat of shellac and repeat in 12
hours. Now the mold is ready to
use.
MOLDING: First always make sure that you have lubricated your mold with
stearine or beeswax.
Place molds on a reasonably level surface and pour the Sulpho-Plastic into
the mold, quickly and
smoothly. Do not pour from a height as this will break the lubricant and
leave blemishes on the
castings. Plastic must be poured quickly to prevent cooling in folds and
thus making a poor casting.
One of the big assets of Sulpho-Plastic is the fact that is dries and
hardens almost immediately. There
is no long wait for the casting to dry.
SOURCES OF SUPPLIES: Graphite and Sulphur can be obtained from most any
hardware or paint
store. Also plaster of paris. Stearine, beeswax, sweet oil can be purchased
from most drug or grocery
stores.
FORMULA:
Foam density lbs./cu.ft.
11/2 8 24 48
Polylite 8601
50. 50. 50. 50.
Catalyst RI
1.3 0.65 0.65 0.65
Water
3.7 0.4 0.1 0.0
Polylite 8621
100. 50. 48.5 47
(polylite 8601 is a polyseter) (polylite 8621 is a polyiscyanate)
PROCEDURE: In order to prepare a foam of give density, thoroughly mix
Polylite 8601 with the
necessary amount of catalyst RI and water. This mixture is stable when foam
is required. Add the
necessary amount of Polylite 8621. Mix thoroughly for 25 to 30 seconds and
then pour. Do this right
after mixing foams per instructions above. The foam will fully expand
within 3 to 5 minutes and set
within 5 to 7 minutes into a rigid unicullar structure.
Available mixing time can be extended by moderately chilling the catalyzed
resin and the
Polysicyanate. It will attain nearly maximum physical properties upon
standing a few hours at room
temperature and ultimate strength in about one week. Surface brittleness
may be evident with some
formulations after initial set. This brittleness disappears upon further
curing, leaving a tough non-friable
foam. curing can be accelerated with moderate heat up to 100 degrees F.
after the foam has set if
desired.
SOURCES OF SUPPLIES: Polylite 8601, Polylite 8621 and Catalyst RI can all
be obtained from:
Reichold Chemicals Inc. 525 N. Broadway, White Plains, NY 10602
CRAFT PLAX CLEAR FLEXIBLE PLASTIC
Vinyl Chloride Type
Suitable for molding in a letter press
FORMULA:
Pliovic AO.......25 ounces
Dioctyl Phthalate.......12 ounces
Panaflex BN 2.....4 ounces
Aluminum Stearate....1 ounce
PROCEDURE: The aluminum stearate is mixed with hot Dioctyl Phthalate. After
cooling to room
temperature, add the panaflex BN 2, and finally, the Pliovic AO. Small
scale mixing can be done with a
paddle, but commercial size batches will require the use of a planetary
dough type mixer such as used
by bakers.
PACKING: One pint paint cans and a paper label.
DIRECTIONS FOR USE: Mold with your hands or press into molds with a letter
press. Heat to 350
degrees F. and hold this temperature until the plastic has cured. This will
require from a few minutes to
an hour or more, depending on the thickness of the object. Curing time can
be determined by trial.
Molds can be made of 50-50 solder.
COMMENT: Plastic of this kind is known as plastigel, since it is in the
form of easily manipulated,
putty-like gel in its uncured state. No other form of plastic is better
suited to the operation of the
homeworker because no expensive dyes or high pressure pressing equipment is
needed to produce first
class flexible objects.
SOURCE OF SUPPLIERS:
Pliovic AO..Goodyear Tire and Rubber Co. Akron, OH. Dioctyl Phthalate..
Monsanto Chemical
Corp...1700 S. 2nd St., St. Louis MO.
Panaflex BN-2..Amoco Chemical Corp..555 Fifty Ave., New York, NY.
Aluminum Stearate..Witco Chemical Co., 277 Park Ave., New York, NY.
Paint Cans..Fruend Can Co., 4439 S. Cottage Grove Ave., Chicago, IL.
Labels..Frazer Label Co., 734 S. Federal St., Chicago, IL. Mixers.. A.
Daigger & Co., 189 W. Kinzie
St., Chicago, IL.
IMITATION PAPER MACHE
FORMULA 1:
Wet paper pulp.....10 ounces
Casein.....5 ounces
Lime.....2 ounces
Whitting.....20 ounces
Use as little water as possible in mixing this formula. Make up small
batches until you see if the
composition is exactly what you desire. Hot compositions, of course cannot
be used in glue molds.
FORMULA 2:
Paper pulp.....10 ounces
Whitting.....8 ounces
Rice flour.....5 ounces
Cook to a heavy paste, or 5 ounces of rice may be cooked to a past and
mixed with the dry materials.
A hard paper mache.
FORMULA 3:
Use paper pulp or whitting...5 pounds
Liquid Glue.....1 pound
Clear Varnish.....4 ounces
Linseed Oil.....4 ounces
MIXING: Pour the glue into a tin or pail with a tight fitting lid so that
it can be kept tightly closed when
not in use. Then add the whitting or paper pulp, stirring in a little at a
time to a smooth paste. Then add
the varnish and linseed oil, mixed well. Keep the mixture covered well when
not in use as it dries
rapidly. This mixture will adhere firmly to wood, glass, tin, chinaware,
etc. paper mache surfaces are
greatly improved after drying if they are coated with shellac, 2 coats.
SYNTHETIC RESIN PLASTIC
FORMULA: Phenol and a solution of Formaldehyde, in equal portions are put
in a steam jacketed
kettle and heat is gradually applied. Soon the materials will begin to
react, and in doing so - liberate heat
so intense the reaction may become that the steam must, at times be shut
off and cold water circulated
in the jacket to keep the process from going too far, or the materials from
boiling out of the kettle.
After a few hours of heating the contents of the kettle will be found to
have separated into layers. The
heavy melted resin n the bottom and the water on top. When the water is
removed, the melted resin is
allowed to run from the kettle into small pans to cool. This is a process
that requires some
experimenting with to get just right. But it is an interesting experience,
and lays the foundation for later
work on a commercial basis. Different treatment will produce many different
qualities of the product.
So it is good to keep a record of every operation. Put them all down in a
record book, when a
satisfactory product is obtained, it can later be duplicated.
SOURCE OF SUPPLIES:
Phenol and Formaldehyde can be purchased from most any wholesale drug
supply Co.
FIBERGLASS REINFORCED PLASTIC
FORMULA:
Laminac 4134........24.45%
Laminac 4110........75.00%
Cobalt Nepthenate (Liquid)...0.24%
Methyl Ethyl Ketone Peroxide...0.3%
ALSO NEEDED:
Talc
Fiberglass mat
Color paste for Laminac resin
Cellophane
No. 1894 EX-L-WAX
Woven Fiberglass cloth
PROCESS:
This method of forming reinforced plastic objects is known as "open mold
fabrication." It is best suited
to the home craftsman because it is the simplest method available and
requires the lowest investment.
Extreme wide variation in the techniques are possible and they type os
structures that can be made are
almost limitless. For molding a boat hull, a female mold is used. This mold
is made to conform exactly
to the exterior dimensions and finish desired in the completed molded boat
hull. The mold may be made
of wood, plaster, metal, or plastic. The best practical and inexpensive
molds are made of the same
plastic from which the boat itself will be made. The interior of the mold
is first coated with the parting
agent - No. 1894 EX-L-WAX. Apply the least amount that will provide easy
removal of the hull from
the mold. Mix the laminac 4134 and 4110 in the proportions stated in the
above formula. Add the cobalt
naphthenate accelerator and mix thoroughly before adding the methyl ethyl
ketone peroxide catalyst.
The catalyst will react violently with the pure accelerator so make certain
these materials are mixed
separately. Add talc to the mixture to thicken it so that application to a
vertical surface will not produce
sags... Apply a coat of the thickened resin to the inside surface of the
mold. This is to insure a smooth
and durable surface. Lay up a single layer of fiberglass mat over the
entire surface of the mold. Using
a paint roller or brush impregnate the layer of fiberglass with resin.
Regardless of how the resin is
applied, the paint roller must also be used to assure against entrapped air
bubbles.
Lay up another layer of mat and impregnate with resin same as the first.
Repeat this process until
desired thickness is attained. Finish with a layer of fiberglass cloth and
work vigorously with the roller
to remove excess resin. Finally apply cellophane over the entire surface to
produce a smooth finish.
Allow to harden at room temperature. Remove from the mold and place in an
even heated oven to 170
degrees F. and not over 200 degrees F. Bake until full hardness is achieved.
Any other structure, large or small is molded in the same way. Whether you
use a male or female mold
depends on which surface of the finished piece should have the finished
side. The surface in contact
with the mold is always the most highly finished.
Colors may be added to suit by using color paste made for the purpose.
These are incorporated into the
resin at the time the talc is added.
More complete instructions on this process may be found in "Fabrication
with Laminac Resins. Write
to: American Cyanamid Co., 30 Rockefeller Plaza, New York, NY 10020.
SOURCES OF SUPPLIES:
Laminac 4134 and Laminac 4110 from..American Cyanamid Co. Plastics Div., 30
Rockefeller Plaza,
New York, NY 10020 Cobalt Nepthenate (liquid) from..Carlisle Chemical
Works, Inc. Reading, OH.
Methyl Ethyl Ketone from..Enjay Co., 15 W. 51st, New York, NY 10020
Talc from... Johns-Manville Co., Celite Div., 22 E. 40th St., New York, NY
10016
No. 1894 EX-L-WAX from...Mitchell Rand Mfg. Co. 51 Murray St., New York, NY
10007
Fiberglass Mat from....Bigelow Fiberglass Products, 140 Madison Ave., New
York, NY 10016
Woven Fiberglass Cloth from....Hess Goldsmith & Co., 1450 Broadway, New
York, NY
Color Pastes from...Plastic Molders Supply Co., 74 South Ave., Fanwood, NJ
Cellophane from...Olin Products Co., 270 Park Ave., New York, NY
FISHING LURES, FROGS & WORMS
FORMULA:
Geen 121..........30 ounces
Geen 202..........20 ounces
Good-Rite GP-261...25 ounces
Tin Stabilizer....1 ounce
Hydrogenated Terphenyl...25 ounces
PROCEDURE:
A small quantity like this may be mixed with an electric hand mixer, or by
hand. This mixture is fluid
and may be poured into suitable molds. Heating the molds to 350 degrees F.
in an oven. It will fuse and
harden the plastic. There will be little shrinkage and the cast objects
have a life-like feeling. Molds may
be made of any material that will stand the curing temperature.
SOURCES OF SUPPLIES:
Geen 121 & 202 from..B.F. Goodrich Chemical Co., 3135 Euclid Ave.,
Cleveland, OH
Good-Rite GP-261 from...B.F. Goodrich Chemical Co., 3135 Euclid Ave.,
Cleveland, OH
Hydrogenated Terphenyl from...Harshaw Chemical Co., 1945 E. 97th St.,
Cleveland, OH
Tin Stabilizer from...Metal Thermit Corp., Rahway, NJ
CELLO SPONGE RUBBER
FORMULA:
Geen 121..........100 ounces
Paraplex G-25........50 ounces
Paraplex G-50........50 ounces
Dythos (stabilizer)....3 ounces
BL-353 (blowing agent)..10 ounces
Sponge Density 7 lbs. per cu. ft. Expansion 1100%.
PROCEDURE:
Heat the pastisol in the mold or on the desired substrate at 212 degrees F.
until expansion is completed.
When the GL-353 is used. The pigmented plastisol will show a yellow-green
(the color of BL-353) to
white when all the blowing agent is decomposed.
SOURCES OF SUPPLIES:
Geen 121 from..B.F. Goodrich, 3135 Euclid Ave., Cleveland, HO
Paraplex G-25 & G-50 from...Relm & Haas Co., Washington Square,
Philadelphia, PA
Dythos from...National Lead Co., 111 Broadway, New York, NY
BL-353 from...E.I. Dupont Co., Wilmington, DE
SIMPLIFIED PLASTICS
The amount of ingredients used in these various formulas is considered to
be correct. But you may
have to do some experimenting on your own, to obtain the proper flow
properties.
FORMULA 1:
Wood Flour...5 parts
Sodium Silicate....15 parts
PROCEDURE:
Mix the wood flour and Sodium Silicate together. Add more water if
necessary until a dough like
mixture is formed by kneading with the hands. This material may be molded
into hard objects by
pressure. Colors may be added while kneading. Use aniline dyes or dry
colors. This material is suited
for plaques, statues, book ends and etc.
FORMULA 2:
Dissolve 20 parts of flake glue in water n a double boiler. Add the
dissolved glue to 90 parts of gelatin.
Add 50 parts of wood flour and 300 parts of powdered chalk. Mix A and B
together to make a heavy
batter. This is done in enough warm water to loosen the material. Add dry
colors (can be obtained
from any paint dealer) and mold under pressure.
FORMULA 3:
Add 100 pars of Zinc Oxide to 4 parts of Silicic Acid. Add 2 parts of
Powdered Borax to 2 1/2 parts of
Powdered Glass. Then mix both together well. Grind until fine, then bring
it into a solution by adding a
concentrated Zinc Oxide solution. This material is ideal for small objects,
but most be worked fast
because of its rapid drying. Color if desired in the usual manner. It may
be pressed with a hand press
or in a drill press.
FORMULA 4:
Dissolve 1 pound of flaked glue in water by boiling. Shred enough tissue
paper into the solution to give
body and then stir until a thick batter results. Add 1 cup of Linseed Oil
into the solution and 1 cup of
powdered chalk. Stir well then remove from the double boiler, when cool
enough to knead with hands.
Press into molds. A pair of old gloves, slightly oiled with pure oil should
be used to protect the hands
while kneading these materials. It takes a few days for this material to
dry. But at the end of the drying
time it should be as hard as stone. And it resembles carved wood.
FORMULA 5:
Add 11 parts of Epsom Salts to 36 parts of freshly Calcined Magnesite and 2
1/1 parts of Lead
Acetate. Mix thoroughly. Then add enough water to hold the material
together. Mold under pressure.
This formula is good for outdoor decorations. Such as ducks, birds, etc.
They may be painted after they
have dried.
FORMULA 6:
Add 12 parts Pitch to 6 parts Rosin, mix together then add 1/2 part Caster
Oil and 1/4 part melted wax.
Blend this mixture together at a temperature of 250 to 260 degrees F. Press
while hot into a cold die.
Many articles may be made from this material.
WOOD PLASTIC
Easy to make. Take any desired amount of wood flour or finely sifted
sawdust. Add enough ordinary
clear lacquer to make a thick putty like mass. This will keep for a long
time if kept in a tightly closed
container. It makes a fine durable material for mending and patching wood.
Purchase a can of plastic wood from your local hardware store. You can see
how it is packaged.
Note: "Plastic Wood" is a registered name. If you wish to package and sell
this product, you cannot use
that name legally. You can make up a name of your own.
Wood Flour may be purchased from....Wood Flour Inc., Howard Street,
Winchester, NH or
Composition Materials Co., Ridgeway Cir, Summer St., Stanford, CT 06905.
You may obtain it from local woodworking plants.
SOURCE OF SUPPLIES:
Metal can may be purchased from...Fruend Can Co., 4439 S. Cottage Grove
Ave., Chicago, IL
Paper labels from...Fraser Label Co., 734 S. Federal St., Chicago, IL
RESIN CASTING PLASTIC
This is called Phenolic-Formaldehyde-Resin: All the materials for this
formula can be purchased from
any wholesale drug house.
EXTREME CAUTION: should be taken when mixing this formula. You should only
use a glass or
stainless steel vessel, and perform the operation in a place where the
fumes will dissipate. Either in
open air or into a chimney. These products should never come into contact
with the skin. They are
highly irritating and corrosive.
MATERIALS NEEDED:
Pure Phenol (carbolic acid) crystals, Formalin (30% Formaldehyde), Caustic
Soda (sodium hydroxide)
or lye, Lactic Acid, Clycerine, and Hydrochloric Acid.
Quantities are given by weight, so that you may make any desired amount of
resin.
FORMULA:
In a vessel mix 1 part phenol with 2 1/2 parts of formalin. Add caustic
soda a 20% solution in water, in
the amount of three parts to 100 parts of the phenol and formaldehyde
solution. This mixture is then
heated for about 6 hours at 150 to 160 degrees F. Remove the water formed
by the reaction. When the
resin has become a thick syrup, add 6 parts of lactic acid and 15 parts of
glycerine. Continue to heat
until a small sample congeals on cooling. Add Hydrochloric Acid, 1 part to
100 parts of the mixture by
weight, and when sufficiently cool, pour into dies of lead or plaster.
Hardening tie depends on so many factors it is hard to predict. It will dry
quicker if heated in an oven
at 120 to 140 degrees F. The product will be water-white, and may be
colored with dyes or pigments if
desired.
HOW YOU CAN SILVER-PLATE OR NICKEL-PLATE WITHOUT ELECTRICITY
SILVERPLATING
To 1 quart of water add the following ingredients:
1 oz. Precipitate Silver
1/2 oz. Cynate of Potash
1/4 oz. Hyposulphite of Soda
Add a little whiting and shake before using.
Apply with a soft rag.
|NICKEL-PLATING
Dissolve in water equal parts of double Nickel salt and Sal Ammonia. Heat
to near boiling point.
Immerse the metal to be nickeled together with some aluminum foil touching
it. Rinse in clear water.