You can estimate the corona-limited maximum voltage for the VDG based 
on the radius of curvature of the top terminal. However, this only 
provides the maximum that the VDG generator could achieve, not 
necessarily what your generator is achieving. The following 
relationship assumes an air breakdown voltage of 30 kV/cm at sea level 
and a polished sphere. The maximum voltage will be reduced for 
locations with higher elevations or if the sphere's surface was not 
polished. The Radius of Curvature (ROC) is in centimeters. So, a 
spherical topload 20 cm in diameter would have a ROC of 10 cm, and an 
estimated maximum VDG voltage of 300,000 volts.
Vmax = 30*ROC
You can also approximate the actual maximum voltage by using a spark 
gap and a suitable table that converts gap distance to voltage. This 
has the advantage of not loading down the VDG until actual spark-over 
occurs. You can use the VDG top terminal as one gap electrode and a 
similarly curved grounded spherical terminal (a gazing globe or a 
metal "float" ball or even a suitably round metal bowl) as the other 
gap electrode. Jim Lux's HV Handbook contains sphere gap construction 
hints and a gap-voltage table:
http://home.earthlink.net/~jimlux/hv/spherev.htm
Bert